Baoxia Mi is working to solve the lead-contamination issue that is inhibiting access to safe drinking water. She and her team discovered that two-dimensional (2D) MoS2 nanosheets are highly effective at removing lead from water. In fact, it is more effective than all materials reported in scientific literature thus far. This can be used as a Point-of use (POU) filter than can be installed in households, making clean water available to communities in need.
Dr. Baoxia Mi is Associate Professor in the Civil and Environmental Engineering Department. Her research focuses on advanced membrane processes and nanotechnology to address some challenging issues in sustainable water supply, including desalination, drinking water quality, wastewater reuse, renewable energy production, and public health protection.
Area of Research
2D Nanomaterial-Enabled Technology for Lead Removal from Drinking Water
Point-of-use (POU) filters that can be installed in households to effectively remove heavy metals (e.g. lead) from drinking water are urgently needed considering recent nation-wide outbreaks of lead contamination of drinking water (e.g., Flint MI, Newark NJ). We discovered that two-dimensional (2D) MoS2 nanosheets demonstrate the highest lead removal capabilities among all materials that have ever been reported in the literature. For example, MoS2 exhibits the highest adsorption capacity as well as the strongest selectivity/affinity toward lead, which are a few orders of magnitude higher than other lead adsorption materials. The high selectivity of MoS2 ensures the successful removal of lead without being interfered by other common ions in drinking water. Filters assembled by stacking MoS2 nanosheets exhibit much higher water productivity than typical reverse osmosis membranes while effectively reducing heavy metal concentration from ppm level to less than 10 ppb. It outperforms other state-of-the-art membranes or novel filters made of various new materials. These results demonstrate that the layer-stacked MoS2 filter has great potential as an innovative POU device for lead removal from drinking water.
The most common sources of lead in drinking water are pipes, faucets and plumbing fixtures. Given the challenges, time and expense of renovating water service infrastructures, the most expedient remedy is to install in households point-of-use filters that can remove lead and other heavy metals from water. Such filters offer flexibility, easy operation and cost-effectiveness. However, materials that provide ultrahigh affinity and selectivity for lead ions have been lacking.
Bakar Fellow Baoxia Mi, an associate professor in the Civil and Environmental Engineering Department, and director of research and educational activities at the Membrane Innovation Laboratory, believes she and her research group have found a solution. An expert on advanced membrane processes and nanotechnology, Mi has focused her research on addressing the challenges to maintaining a healthy and sustainable water supply, including in addition to drinking water quality, desalination, wastewater reuse, renewable energy production, and public health protection.
Most recently, Mi and her group discovered that two-dimensional sheets only a few nanometers thick of molybdenum disulfide (MoS2), a semiconductor highly touted for its potential in energy storage and electronic devices, shows the highest lead removal capabilities of any material ever reported. They’re now developing a point-of-use water filter based on stacked layers of MoS2 nanosheets that could provide households with affordable, super-effective protection from lead contamination as well as from other dangerous heavy metals.
Q: Why did you decide to focus your research on issues pertaining to drinking water and what prompted you to test MoS2 as a potential filtering material?
A: My academic training is in water quality engineering, so naturally I’m interested in any technology that may improve the quality of our drinking water. I became interested in using MoS2 as a filter material after learning that it provides strong binding to a number of heavy metal ions including lead.
Q: How does your MoS2 water filter compare to existing point-of-use filtration systems?
A: We’ve demonstrated that stacking layers of MoS2 nanosheets enables our filter to outperform all commercially available point-of-use filtration systems by a wide margin. Our filter has a much higher lead adsorption capacity and is much more selective for lead over other ions common to drinking water. In addition, a 500 nanometer thick MoS2 filter allows for a high water flow rate while effectively reducing lead concentration in drinking water a thousand fold, from parts per million to less than 10 parts per billion.
Q:What makes your filter so much more effective than other systems?
A: Our filter maintains a stable spacing of approximately 1.2 nanometers between each layer of MoS2. This yields an ultrahigh surface area that exposes all of the sulfur atoms on each nanosheet as accessible lead-binding sites.
Q: In addition to high lead adsorption capacity and selectivity, does your MoS2 filter hold other advantages over current point-of-use filters?
A: Yes, low energy costs, affordability, and convenience are among the most salient of additional advantages. Our MoS2 filter reduces energy demands by delivering a high rate of water flux at low pressure. The material cost is low and the filter can be repeatedly used through regeneration with little maintenance required.
Q: What is the next step for developing your MoS2 filter?
A: First we’ll construct a prototype with the capability of filtering 10 liters (about 2.6 gallons) of water per hour. This prototype will be tested over a full spectrum of tap water chemistry, and its MoS2 layers will be regenerated for repeated use of the filer. We’ll also create a model to evaluate the tradeoffs of key design and operation parameters. Over the next couple of years we plan to evaluate the performance of the prototype in filtering real tap water and wastewater with added heavy metals to mimic contamination events. The water production rate, heavy metal removal efficiency, membrane fouling, and other key operational parameters will be continuously monitored for at least two months, and the lifetime of the device will be estimated based on these results.
Q: How will your Bakar Spark Fund be used in this effort?
A: Our Bakar Spark funding will allow us to more thoroughly evaluate the performance of our filter and tackle the key challenges of scaling up the technology for the commercial market.